Roman O. Scherbyna , OleksandrI. Panasenko, Evgeniy G. Knysh, Alla. S. Korzhova.. The Research «ring-chain⻠Tautomerism Of 2-(1-h-1,2,4-triazol-5-ylthio)acetaldehydes
Natural Sciences / Chemistry / Organic chemistry
Submitted on: Apr 22, 2013, 03:26:49
Description: Due to the complex using of instrumental methods of analysis(GC-MS, IR, 1H NMR, X-ray) and chemical reactions (condensation, recovery, cyclization) is set a presence of «ring-chain» tautomerism in 2-((3-phenyl-1H-1,2,4-triazol-5-yl)thio)acetaldehyde (1Ð.). As a result of the research revealed, that in solid form is dominated a «ring»-form, and in solution - a «chain»-form. Also, in a result of the X-ray research is revealed a crystal structure of 3-phenyl-5,6-dihydrothiazolo[2,3-c][1,2,4]triazol-5-ol.
The full-text article has been published in the "IntellectualArchive" journal , Vol.2, Num.3, May 2013, ISSN 1929-4700.